羧酸盐对锡和铝在中性溶液中的缓蚀作用研究

分别采用交流阻抗、线性极化、动电位扫描等电化学方法初步研究了羧酸盐缓蚀剂在中性介质中对锡和铝的缓蚀作用.实验结果表明,锡和铝在中性介质中的腐蚀以点蚀为主,而该羧酸盐结构中含有羧基,对锡和铝有良好的缓蚀效果,尤其是处于最佳缓蚀浓度时.     

不锈钢面板与铝面板泡沫铝夹芯梁的抗爆性能

为考查泡沫铝夹芯梁的抗爆性能及面板材料对其抗爆性能的影响，采用数值模拟方法分析了面板材料分别为工业纯铝与304号不锈钢，芯材为Alporas泡沫铝共同组成相同质量泡沫铝夹芯梁在不同爆炸荷载作用下的跨中位移与芯材压缩应变的差异。研究结果显示：在爆炸冲量分别为1．82，3．77，6．08，7．0kN·s的作用下，工业纯铝面板泡沫铝夹芯梁跨中位移分别为304号不锈钢面板泡沫铝夹芯梁跨中位移的68％，83％，84％及86％，较304号不锈钢面板泡沫铝夹芯梁具有更好地抵抗爆炸冲击波的能力，面板材料对泡沫铝夹芯梁的压缩应变影响较小。     

铝合金-纯铝-钢复合板爆炸焊接试验及性能研究

通过设计爆炸焊接试验复合了铝合金-纯铝-钢爆炸复合板,对其界面形态、显微硬度及力学性能进行了研究。结果表明,铝合金-纯铝界面纯规则正弦波形,纯铝-钢复合板界面波形较小,铝合金-纯铝-钢复合板的界面剪切强度在75 MPa以上,爆炸复合过程中,纯铝与钢界面生成了金属间化合物,其界面处基体金属发生强烈的塑性变形。复合板变形及组织变化的结果造成复合板界面处的显微硬度最高,随着距界面距离的增加,两侧基体金属的硬度逐渐降低。     

稀土离子La~(3+)、Ce~(3+)对铝合金孔蚀的缓蚀作用实验分析

用电化学方法研究了稀土离子La~(3+)、Ce~(3+)对铝合金LY12CZ在中性含Cl~-离子水溶液中对孔蚀行为的缓蚀作用,测定了孔蚀电位E_b,保护电位E_p以及诱导时间等,结果表明,两种离子对铝合金LY12CZ的孔蚀均有较好的缓蚀作用。并进行了机理分析。     

几种缓蚀剂对低合金钢在海水中的缓蚀行为的研究

研究了几种含氨基、羟基的缓蚀剂在3%NaCl溶液中对低合金钢的缓蚀行为.运用线性极化技术测定比较几种缓蚀剂的缓蚀效果.动电位极化曲线、交流阻抗测量表明,几种缓蚀剂均为阳极型缓蚀剂,添加后由于缓蚀剂吸附在金属表面,从而有效地抑制了低合金钢的腐蚀.     

中性水中铸铁和铸铝的缓蚀行为研究

以合成的磷酸醇胺与钼酸盐为缓蚀剂的主要成分,并且分别复配羧酸、胺,设计出4种体系,采用失重法和电化学方法研究它们在中性水中对铸铁及铸铝的缓蚀作用.实验结果表明,浓度高的磷酸醇胺有着良好的缓蚀性能,添加羧酸对铸铝有很好的效果,添加胺对铸铁有很好的效果.并且初步探讨了缓蚀机理.     

强磁场对Sn-3Ag-O.5Cu/Cu扩散偶界面金属间化合物生长的影响

研究了强磁场对Sn-3Ag-0.5Cu/Cu扩散偶界面金属间化合物生长的影响.结果表明:在强磁场作用下,Sn-3Ag-0.5Cu/Cu扩散偶在170 ℃时效过程中其界面金属间化合物的生长规律与无磁场作用时相同.但强磁场作用下界面金属间化合物的生长速率较无磁场作用时有所增加.通过比较正反向强磁场对界面金属间化合物生长的影...     

有机羧酸在中性腐蚀介质中对铸铝的缓蚀性能研究

通过电化学方法研究了不同浓度的有机羧酸对偶接及非偶接状态下铸铝的缓蚀性能,并对其缓蚀机理作了初步探讨.结果表明:常温状态下,该有机羧酸对铸铝有着很好的缓蚀效果,且随着其浓度的提高,缓蚀效果增加.此缓蚀剂对铸铝主要表现为几何覆盖效应,为抑制阳极型缓蚀剂.     

恒电量微扰法研究在含Cl-介质Ce3+对航空铝材的缓蚀作用

本文用恒电量微扰法研究了Ce3+对铝合金在0．1mol·L-1NaCl介质中的缓蚀机理及抗孔蚀性。结果表明：铝合金孔蚀诱导过程及其表面形成林转化膜过程具有相同的电化学模式,电化学腐蚀速度控制步骤取决于钝化膜（转化膜）／溶液界面过程。Ce3+对铝合金孔蚀的诱导期和发展期均有抑制作用,形成铈转化膜后,铝基表面阻抗大大提高,耐孔蚀性增强。     

对充分发挥德育功能的认识

<正>当今,在对德育的理解上有两种片面的倾向,一种是认为德育就是道德教育,或者说,德育就是道德品质教育的简称.这种理解在我国由来已久,中国古代教育家,从孔子开始就把学道传道放在教育的首位,所谓“修身”的说法,就是一种道德教育.这种纯道德教育观,抽掉了德育的政治内容,从而否定了教育的阶级性.     

活塞环表面CrTiAlN复合涂层的抗高温腐蚀性能研究

采用多弧离子镀技术,利用Cr靶和TiAl靶,在活塞环材料65 Mn钢基体上制备了CrTiAlN复合涂层,并对电镀Cr、CrN和CrTiAlN复合涂层在800℃下的抗高温腐蚀性能进行了比较分析,用扫描电镜、能谱仪和X射线衍射仪观察分析了样品表面高温腐蚀氧化膜。结果表明:CrTiAlN复合涂层具有优异的抗高温腐蚀性能,在800℃时仍具有良好的抗高温腐蚀性能,其氧化机理是O向涂层内部扩散氧化,在高温腐蚀过程中,CrTiAlN涂层中的Cr发生了选择性氧化,优先形成了Cr2O3,CrTiAlN涂层氧化层区域的结构由外至里组成顺序为Cr2O3、Al2O3+TiO2、(Cr,Ti,Al)N。涂层外层的Cr2O3氧化物有利于阻碍氧元素向涂层内部扩散,能够降低涂层的高温腐蚀速度。     

几种气相缓蚀剂组分间协同作用研究

采用气相防锈甄别实验及量子化学计算方法对钼酸铵、亚硝酸钠、苯甲酸、苯甲酸钠、肉桂酸和肉桂酸钠等6种气相缓蚀剂的气相防锈能力和组分之间的协同作用进行研究．结果表明,4种单组分盐类物质本身不具备气相防锈能力,但2种无机盐和2种有机盐之间具有良好的协同效应．从防锈效果上看,钼酸铵完全可以代替亚硝酸钠,但由于其用量较高,成本上会高于传统的亚硝酸钠系气相缓蚀剂．     

Effects of material of metallic frame on the penetration resistances of ceramic-metal hybrid structures

The effects of metallic material on the penetration resistances of ceramic-metal hybrid structures against vertical long-rod tungsten projectiles were studied by artillery-launched experiments and numerical simulation. Hybrid structures with rectangular cores in transverse orthogonal arrangement and slide-fitting ceramic inserts of zirconia toughened alumina prisms were fabricated with titanium alloy TC4 (Ti6Al4V), AISI 4340 steel and 7075 aluminum alloy panels, respectively. The results showed that the hybrid structure of Ti6Al4V exhibited the highest penetration resistance, followed by that of 7075 aluminum alloy with the same area density. The penetration resistance of the hybrid structure of AISI 4340 steel was the lowest. The underlying mechanisms showed that the metallic material of a ceramic-metal hybrid structure can directly affect its energy absorption from the impact projectile, which further affects its penetration resistance. Different metallic frames exhibited different failure characteristics, resulting in different constraint conditions or support conditions for ceramic prisms. The high penetration resistance of the Ti6Al4V hybrid structure was due to its stronger back support to ceramic prisms as compared with that of AISI 4340 steel hybrid structure, and better constraint condition for ceramic prisms by metallic webs as compared with that of 7075 aluminum alloy hybrid structure. The results of mass efficiency and thickness efficiency showed that the Ti6Al4V hybrid structure has advantages in reducing both the thickness and the mass of protective structure. In addition, because the ceramic-metal hybrid structures in the present work were heterogeneous, impact position has slight influence on their penetration resistances.     

氯酸钾对不锈钢在硫酸和盐酸混合溶液中的缓蚀行为

研究了缓蚀剂ＫＣｌＯ３在７０％Ｈ２ＳＯ４和０．２％ＨＣｌ溶液中对１８—８不锈钢的缓蚀行为。运用线性极化技术测定了缓蚀剂的缓蚀效率为９６％。动电位极化曲线、循环极化曲线及交流阻抗的测量表明,缓蚀剂ＫＣｌＯ３是一种阳极钝化型缓蚀剂,添加缓蚀剂ＫＣｌＯ３后,不锈钢表面氧化膜进一步加强,从而有效地抑制不锈钢的均匀腐蚀和孔蚀。     

Effect of particle gradation of aluminum on the explosion field pressure and temperature of RDX-based explosives in vacuum and air atmosphere

To optimize the energy output and improve the energy utilization efficiency of an aluminized explosive, an explosion device was developed and used to investigate the detonation pressure and temperature of R1 (Al6) aluminum powder and the aluminum powder particle gradation of R2 (Al6+Al13), R3 (Al6+Al24) and R4 (Al6+Al flake) in a confined space. By using gas chromatography, quantitative analysis and calculations were carried out to analyze the gaseous detonation products. Finally, the reaction ratios of the aluminum powder and the explosion reaction equations were calculated. The results show that in a confined space, the quasi-static pressures and equilibrium temperature of the aluminum powder in air are higher than in vacuum. In vacuum, the quasi-static pressures and equilibrium temperatures of the samples in descending order are R1>R3>R4>R2 and R3>R4>R1>R2, respectively. In air, the quasi-static pressures and equilibrium temperatures of the samples in descending order are R1>R2>R4>R3 and R1>R4>R2>R3, respectively. R4 (Al6+Al flake) and R3 (Al6+Al24) have relatively higher temperatures after detonation, which shows that the particle gradation method can enhance the reaction energy output of aluminum during the initial reaction stage of the explosion and increase the reaction ratio by 10.6% and 8.0%, respectively. In air, the reaction ratio of Al6 aluminum powder can reach as high as 78.16%, and the reaction ratio is slightly reduced after particle gradation. Finally, the reaction equations of the explosives in vacuum and in air were calculated by quantitative analysis of the explosion products, which provides a powerful basis for the study of RDX-based explosive reactions.     

喷气燃料中硫化物对银片腐蚀的量化表征

银片腐蚀主要受喷气燃料中硫化物的影响,不同种类、结构的硫化物对银片腐蚀的影响不同,从喷气燃料中硫化物系统角度来研究对银片腐蚀影响是很有意义的。采用量化自组织神经网络从定性、定量两个方面研究喷气燃料中硫化物对银片腐蚀的影响,研究结果表明,能够从喷气燃料硫化物的存在情况来预测银片腐蚀结果。     

Shock-induced reaction behaviors of functionally graded reactive material

In this paper, the ballistic impact experiments, including impact test chamber and impact double-spaced plates, were conducted to study the reaction behaviors of a novel functionally graded reactive material (FGRM), which was composed of polytetrafluoroethylene/aluminum (PTFE/Al) and PTFE/Al/bismuth trioxide (Bi₂O₃). The experiments showed that the impact direction of the FGRM had a significant effect on the reaction. With the same impact velocity, when the first impact material was PTFE/Al/Bi₂O₃, compared with first impact material PTFE/Al, the FGRM induced higher overpressure in the test chamber and larger damaged area of double-spaced plates. The theoretical model, which considered the shock wave generation and propagation, the effect of the shock wave on reaction efficiency, and penetration behaviors, was developed to analyze the reaction behaviors of the FGRM. The model predicted first impact material of the FGRM with a higher shock impedance was conducive to the reaction of reactive materials. The conclusion of this study provides significant information about the design and application of reactive materials.     

回归再时效7A60铝合金在0.5mol/L NaCl溶液中的点蚀性能

采用腐蚀电化学的点蚀极化曲线并结合腐蚀形貌的扫描电镜分析的方法,研究了回归再时效(RRA)工艺处理7A60铝合金在0.5mol/L NaCl溶液中的点蚀行为,对其耐点蚀性能进行了评价,并探讨了RRA工艺改善该合金点蚀性能的机理。结果表明:采用120RRA工艺(120℃×24h预时效+195℃×0.5h回归+120℃×24h再时效)处理后,7A60铝合金在0.5mol/L NaCl溶液中的阳极极化曲线闭合环面积减小,再钝化电流密度Ipp降低,蚀孔较浅,RRA工艺在一定程度上改善了该铝合金在0.5mol/L NaCl溶液中的耐点蚀性能。