夹杂物对有机涂层下碳钢腐蚀初期过程的影响

选择两种具有典型夹杂物的碳钢,通过浸泡试验,研究有机涂层下碳钢的腐蚀初期过程,并和裸钢的腐蚀过程进行对比．结果表明：涂层试样和裸钢试样腐蚀发展的初期过程都是点蚀;涂层试样点蚀诱发孕育期大大长于裸钢试样;点蚀的主要诱发源是钢中的硫化物和硅酸盐;硫化物夹杂物诱发点蚀及点蚀的扩展主要沿夹杂物与基体间的相界进行．     

用电化学方法评价油膜防锈性能

用电位—时间、多重动电位扫描两种电化学方法对防锈油的防护性能进行了分析和评价 ,并与盐水浸渍试验进行了对照。结果表明 :两种电化学方法不仅与盐水浸渍试验具有良好的相关性 ,而且能够反映油膜下金属腐蚀的细微特征 ,是研究和评价防锈油较好的方法     

超细干粉自动灭火装置在民用建筑中的应用前景分析

指出了超细干粉和超细干粉自动灭火装置的技术特点,并通过与其他自动灭火系统的比较,分析了超细干粉自动灭火装置在民用建筑中的应用前景。     

反应法制备SiC涂层组成与结构

采用反应法在C/SiC复合材料表面制备SiC致密涂层,利用XRD分析涂层的组分及晶体结构,利用扫描电镜及金相显微镜观察涂层的断口及表面形貌,并对涂层形成过程进行了分析。结果显示:涂层主要由SiC及少量的游离Si组成,致密不开裂的SiC涂层与C/SiC复合坯体之间有很好的梯度过渡结构;相反,涂层与坯体之间如果没有形成过渡层,涂层会因热残余应力过大而开裂;反应法制备不开裂SiC涂层与CVDSiC涂层有很好的热匹配性,同时在其表面制备的CVDSiC涂层无点缺陷。     

添加型防静电涂料的研究进展

对添加型防静电涂料的组成、导电机理、导电填料的研究状况进行了综述,重点论述了导电填料的研究重点和发展方向.白色和浅色导电填料是未来添加型防静电涂料的重点研究对象.     

镁合金表面电弧喷涂Fe基非晶纳米晶涂层的性能

采用自动化高速电弧喷涂技术在镁合金基体上制备了FeCrBSiMoNbW非晶纳米晶涂层。采用Flir A20M型红外热像仪对Fe基非晶纳米晶喷涂层的表面温度场进行了实时监测。对Fe基非晶纳米晶涂层和传统的3Cr13涂层的组织结构、力学性能以及摩擦学性能进行了对比分析。实验结果表明：Fe基非晶纳米晶涂层组织致密,孔隙率低,具有相对较高的硬度和拉伸结合强度;形成了非晶相和纳米晶相组成的复合结构,使得涂层具备较好的耐磨减摩性能。     

Storage life prediction under pre-strained thermally-accelerated aging of HTPB coating using the change of crosslinking density

In order to predict the storage life of a certain type of HTPB (hydroyl-terminated polybutadiene) coating at 25 C and analyze the influence of pre-strain on the storage life, the accelerated aging tests of HTPB coating at 40 C, 50 C, 60 C, 70 C with the pre-strain of 0%, 3%, 6%, 9%, respectively were carried out. The variation regularity of the change of crosslinking density was analyzed and the aging model of HTPB coating under pre-strained thermally-accelerated aging was proposed. The storage life of HTPB coating at 25 C was estimated by using the Berthelot equation as the end point of the aging life with a 30% decrease in maximum elongation. The results showed that the change of crosslinking density of HTPB coating increased with the increase of aging temperature and aging time, and decreased with the in-crease of pre-strain. Under 0% pre-strain, the relationship between the change of crosslinking density of HTPB coating and the aging time can be described by the logarithmic model with the confidence probability greater than 99%.The stress relaxation phenomenon existed under 3%, 6% and 9% pre-strained aging. The aging model considering chemical aging and pre-strain was established with the confidence probability greater than 90%. The storage life of HTPB coating was 15.2935 years at 25 C under 0% pre-strain, which was reduced by 13.9007%, 75.6949% and 89.7859% under 3%, 6% and 9% pre-strain, respectively. The existence of pre-strain has a serious impact on the storage life of HTPB coating, therefore, the pre-strain should be avoided as much as possible during the actual storage.     

Buckling analysis of embedded graphene oxide powder-reinforced nanocomposite shells

In this study, the buckling analysis of a Graphene oxide powder reinforced (GOPR) nanocomposite shell is investigated. The effective material properties of the nanocomposite are estimated through Halpin-Tsai micromechanical scheme. Three distribution types of GOPs are considered, namely uniform, X and O. Also, a first-order shear deformation shell theory is incorporated with the principle of virtual work to derive the governing differential equations of the problem. The governing equations are solved via Galerkin's method, which is a powerful analytical method for static and dynamic problems. Comparison study is performed to verify the present formulation with those of previous data. New results for the buckling load of GOPR nanocomposite shells are presented regarding for different values of circumfer-ential wave number. Besides, the influences of weight fraction of nanofillers, length and radius to thickness ratios and elastic foundation on the critical buckling loads of GOP-reinforced nanocomposite shells are explored.     

An interface shear damage model of chromium coating/steel substrate under thermal erosion load

The Cr-plated coating inside a gun barrel can effectively improve the barrel's erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gun-powder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel's inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface's ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.     

陶瓷/金属梯度热障涂层的制备及性能评价

为了评价陶瓷/金属梯度热障涂层的性能,设计了4种涂层方案和2种基体材料(1Cr18Ni9Ti和2Cr13).利用单枪单送粉器成功地制备了线性梯度涂层.通过观察涂层的微观结构、测量涂层的抗热震性能和热残余应力来评价涂层的性能.利用扫描电镜对各种陶瓷涂层的微观结构进行了观察和分析,利用X射线能谱分析得到了陶瓷梯度涂层试样中的不同区域的衍射图.热震试验表明,梯度涂层比非梯度涂层具有更好的抗热震性能.采用钻孔法对不同涂层方案进行了残余应力的测量,结果表明,压应力出现在1Cr18Ni9Ti基体材料上,而拉应力出现在2Cr13基体材料上.