Theoretical study of an energetic material di-1H-1,3,4-triazole derivatives

Computations by density functional theory (DFT) method are performed on a series of di-1H-1,3,4-triazole derivatives with different substituents and linkages. The heat of formation (HOF) is predicted by the designed isodesmic reactions. The predicted results reveal that –N₃ and –NN– groups are effective structural units for increasing the HOF values of the di-1H-1,3,4-triazole derivatives. The HOMO–LUMO gap is affected by the substituents and linkage groups. Detonation performance is evaluated using the Kamlet–Jacobs approach based on the calculated density and HOF. The results indicate that –NO₂, –NF₂, –NH–, –NH–NH– and –NN– groups are helpful for enhancing the detonation properties of di-1H-1,3,4-triazole derivatives. The bond dissociation energy and bond order of the weakest bonds are analyzed to investigate their stability. It is observed that the –CH₂–, –CH₂–CH₂– and –CHCH– groups are effective structural units for improving the stabilities of these derivatives. Considering the detonation performance and the stability, five compounds are screened as the potential candidates for high energy density materials.     

雷达虚拟维修训练中交互系统的通用性

基于USB接口技术对"通用雷达装备虚拟维修训练系统(URVMTS)"的人机交互系统进行研究,通过合理的软、硬件设计实现了系统的通用性。不同的实装操作部件经过适当的信号调理均可以通过该系统方便地实现与雷达虚拟样机之间的交互。着重介绍了交互系统的通用性设计与实现方法,包括系统的通用性设计方案,USB硬件电路的通用性设计及相应的软件开发。     

A Question of ‘Government’ Control: Afghanistan DDR Programs Since 2001

Since the fall of the Taliban in late 2001, the Islamic Republic of Afghanistan (GIRoA), the United States, the United Nations, and the International Security Assistance Force (ISAF) have funded and led three different Disarmament, Demobilization, and Reintegration (DDR) programs. Despite a significant investment in time and treasure, all of them have failed to significantly reduce the number of insurgents or arbaki (militia). This article explores why these programs failed despite incorporating ideas from the prominent DDR schools of thought. Utilizing Stathis Kalyvas’ theory of The Logic of Violence in Civil War as a lens, this article argues that GIRoA and ISAF did not have sufficient control of territory to entice insurgents or arbaki to reconcile and/or reintegrate with the government. Further, in areas GIRoA nominally controlled in northern and western Afghanistan, regional powerbrokers who controlled these areas balked at these programs.     

公安高校计算机基础课程关联性分析

对＂1＋X＂双层课程体系下的计算机基础课程之间的关联性进行初步分析,揭示了教学目标一致性、教学内容互相渗透、人才培养逐层连续性等特点。     

The effects of model parameter deviations on the variance of a linearly filtered time series

We consider a general linear filtering operation on an autoregressive moving average (ARMA) time series. The variance of the filter output, which is an important quantity in many applications, is not known with certainty because it depends on the true ARMA parameters. We derive an expression for the sensitivity (i.e., the partial derivative) of the output variance with respect to deviations in the model parameters. The results provide insight into the robustness of many common statistical methods that are based on linear filtering and also yield approximate confidence intervals for the output variance. We discuss applications to time series forecasting, statistical process control, and automatic feedback control of industrial processes. © 2010 Wiley Periodicals, Inc. Naval Research Logistics, 2010     

基于层间嵌入式多级支持向量机的特征选择

针对多故障样本一次性映射之后分类不理想,研究了多级层次式支持向量机,应用UCI数据仿真,结果表明该方法缩短了训练时间、提升了测试准确率、改善了样本的可分类性。由于误差积累,在此基础上,提出了层间嵌入式多级支持向量机,采用Abalone数据仿真,结果表明分类精度有所提高并减少了分类步骤。结合ReliefF算法,对制导设备的故障特征参数进行了选择。     

基于改进遗传算法的平流层飞艇定点悬停控制(英文)

平流层飞艇定点悬停控制是飞艇应用领域的关键技术。该控制问题可以转化为非线性多目标优化问题来求解。遗传算法是解决现代非线性多目标优化问题的一种重要方法。但是基本遗传算法在解决定点悬停飞艇实际控制问题时,具有易陷入局部最优解、在遗传进化过程中随机性较强、搜索效率低下及耗时多等缺陷。通过借鉴并行遗传算法、模拟退火算法和向量评价遗传算法的基本思想,在基本遗传操作中添加切断算子和拼接算子,设计一种改进遗传算法来改善上述缺陷。仿真结果表明该方法是有效可行的。     

氮化硼先驱体的合成及其热分解特性

以硼氢化锂和硫酸铵为原料合成了氮化硼陶瓷先驱体环硼氮烷,以GC MS、FT IR和1H NMR等方法对其组成和结构进行了表征和确认.环硼氮烷在80℃左右保温72h后可以得到固化的聚硼氮烷,而后经热分解得到氮化硼陶瓷,以TG、FT IR、XRD等对聚硼氮烷的热分解行为进行了分析和表征.结果表明聚硼氮烷中仍然存在一定数量的B H和N H键,在后续的热分解过程中,会进一步发生脱氢反应,1400℃时陶瓷产率约为89.5%.B H键的断裂主要发生在800℃以前,N H键的消失则需要较高的温度.聚硼氮烷800℃热分解后无机化程度已经较高,其产物基本上为无定形的BN,在1600℃则形成h BN.     

一种基于0-1整数规划的全局数据分布优化方法

数据分布是影响并行程序在分布主存多处理机上执行性能的重要因素.针对分布主存多处理机中的数据分布问题,提出了一种基于0-1整数规划、利用数据变换技术进行有效数据分布的方法.该方法通过数据变换技术改变数据的存储布局,以使得数据能被有效地分布,并且该方法还利用数据分布图描述程序被并行的情况及其所含数组被访问的情况,并将全局数据分布优化问题转换为求解数据分布图中最优路径的问题,从而可用0-1整数规划求解最优路径问题.该方法能对多个嵌套循环中具有仿射数组下标的任意维数组进行有效的数据分布,并且也能使嵌套循环的并行度尽可能地大.另外,该方法也考虑了偏移常量的对准问题,从而能使数据通信量尽量地小.实验结果验证了该方法的有效性.     

Burning rate and other characteristics of strontium titanate (SrTiO3) supplemented AP/HTPB/Al composite propellants

In a quest of search for a new burning rate modifier for composite propellant, strontium titanate (SrTiO₃), a perovskite oxide has been chosen for evaluation in a composite propellant formulation based on its other catalytic applications. Initially, SrTiO₃ was characterized for particle size, morphology and material/phase identification (using XRD). By varying SrTiO₃ content in a standard composite propellant, different compositions were prepared and their performance and processing parameters like the end of mix (EOM) viscosity, mechanical properties, density, burning rate, pressure exponent (n-value), etc. were measured. The results reveal that 2% SrTiO₃ causes more than 12% enhancement in propellant burning rate (at 70 ksc pressure) in comparison to the standard propellant composition. The pressure exponent also increases to 0.46, whereas the standard composition was having its value as 0.35.