具有离解反应的推进剂高压蒸发理论探讨

文中提出了具有液相离解反应的推进剂液滴高压蒸发模型,同时还考虑了燃气中极性气体成份对液滴蒸发的影响,并以N_2O_4推进剂液滴为例分析了具有液相离解反应的推进剂蒸发规律。结果表明,此类推进剂高压蒸发并不服从非液相离解反应推进剂的t_b～(?)。规律。模型的提出为液体火箭发动机燃烧室燃烧过程分析提供了新的液滴蒸发理论数据和计算方法。     

Investigation of the shock compression behaviors of Al/PTFE composites with experimental and a 3D mesoscale-model

The responses of AI/PTFE reactive materials (RMs) under shock compression were investigated by a single-stage gas gun.A 3D mesoscale-model was established based on micro-computed tomography(micro-CT) slice images and confirmed with experimental results.In the high-pressure stage,the com-posites reacted partially,whereas there were no deviations between the partially reacted Hugoniot and the inert simulation results.The simulation reveals that the Teflon matrix melting on the high shock pressure.Melts and decomposition of the PTFE accelerated the diffusion of the atoms.Thus,the reactions of the Al/PrFE composites are more like a combustion rather than a detonation.     

Reaction characteristic of PTFE/Al/Cu/Pb composites and application in shaped charge liner

In this paper, the reaction characteristic and its application in shaped charge warhead of a novel reactive material, which introduced copper (Cu) and plumbum (Pb) into traditional polytetrafluoroethylene/aluminum (PTFE/Al), are studied. The thermal analysis and chemical reaction behavior of the PTFE/Al/Cu/Pb mixture are investigated by Differential Scanning Calorimetry (DSC),Thermo-gravimetry (TG), and X-ray Diffraction (XRD) techniques. Then, the shaped charge liners with PTFE/Al/Cu/Pb reactive materials are fabricated, and the X-ray experiments show that they could form reactive jets with excellent performance under the detonation effects of the shaped charge. Based on that, the penetration experiments of shaped charge with PTFE/Al/Cu/Pb reactive liner against steel plates are carried out, and the results demonstrate that the PTFE/Al/Cu/Pb reactive jets could produce a deeper penetration depth compared to the traditional PTFE/Al reactive jets. Meanwhile, the PTFE/Al/Cu/Pb reactive jets also show significant inner-blast effects, leading to dramatically cracking or fragmentation behavior of the penetrated steel plates. This new PTFE/Al/Cu/Pb reactive liner shaped charge presents enhanced penetration behavior for steel targets that incorporates the penetration capability of a high-density and ductility jet, and the chemical energy release of PTFE-matrix reactive materials.     

H2O2/HTPB固液混合发动机点火试验研究

利用H2O2催化分解原理,设计了烃类燃料在催化分解的90%H2O2中能燃烧的点火器,然后采用该点火器进行H2O2/HTPB固液混合发动机点火试验研究.试验结果表明,该点火器能够成功启动H2O2/HTPB固液混合发动机,且当混合比偏离最佳混合比后,发动机的燃烧效率降低.     

Controllable combustion behaviors of the laser-controlled solid propellant

Microsatellites have been widely applied in the fields of communication,remote sensing,navigation and science exploration due to its characteristics of low cost,flexible launch mode and short development period.However,conventional solid-propellant have difficulties in starting and interrupting combustion because combustion is autonomously sustained after ignition.Herein,we proposed a new type of solid-propellant named laser-controlled solid propellant,which is sensitive to laser irradiation and can be started or interrupted by switching on/off the continuous wave laser.To demonstrate the feasibility and investigate the controllable combustion behaviors under different laser on/off conditions,the combus-tion parameters including burning rate,ignition delay time and platform pressure were tested using pressure sensor,high-speed camera and thermographic camera.The results showed that the increase of laser-on or laser-off duration both will lead to the decrease of propellant combustion performance during re-ignition and re-combustion process.This is mainly attributed to the laser attenuation caused by the accumulation of combustion residue and the change of chamber ambient temperature.Simultaneously,the multiple ignition tests revealed that the increased chamber ambient temperature after combustion can make up for the energy loss of laser attenuation and expansion of chamber cavity.However,the laser-controlled combustion performance of solid propellant displayed a decrease trend with the addi-tion of ignition times.Nevertheless,the results still exhibited good laser-controlled agility of laser-controlled solid propellant and manifested its inspiring potential in many aspects of space missions.     

Combustion of B4C/KNO3 binary pyrotechnic system

Presented herein is an experimental study on the combustion of B4C/KNO3 binary pyrotechnic system.Combustion products were tested using X-ray diffraction(XRD),scanning electron microscopy(SEM),and energy dispersive spectrometer(EDS).According to the results of tests and CEA calculation,the combustion reaction equation was established.The flames and burning rates were recorded by a high speed camera and a spectrophotometer.The effect of B4C particle size on the thermal sensitivity of B4C/KNO3 was investigated by differential scanning calorimetry(DSC)techniques.In addition,a reliable method for calculating the flame temperature was proposed.Based on the results of experiments,the combustion reaction mechanism was briefly analyzed.The burning rate,flame temperature and thermal sensitivity of B4C/KNC3 increase with the decrease of B4C particle size.The mass ratio of B4C/KNO3 has a great effect on combustion properties.Oxidizer-rich compositions have low flame temperatures,low burning rates,and provide green light emission.The combustion reactions of fuel-rich compositions are vigorous,and the B4C/KNO3 with mass ratio of 25:75 has the highest burning rate and the highest flame temperature.     

嵌银丝贫氧推进剂燃烧特性

采用试验发动机法 ,对嵌银丝铝镁贫氧推进剂的燃烧特性进行了研究 ,得到了低压下嵌银丝铝镁贫氧推进剂的燃烧规律 ,研究了银丝直径和贫氧推进剂配方对嵌银丝发动机燃速的影响。结果表明 ,嵌银丝贫氧推进剂的燃烧过程由初始工作段、稳定工作段和结束段组成 ;采用较粗的银丝 (0 3mm和0 4mm)可以显著提高贫氧推进剂的燃速 ;提高贫氧推进剂的基础燃速也是提高嵌银丝贫氧推进剂燃速的有效方法之一。     

Numerical simulation of base flow with hot base bleed for two jet models

In order to improve the benefits of base bleed in base flow field, the base flow with hot base bleed for two jet models is studied. Two-dimensional axisymmetric Navier–Stokes equations are computed by using a finite volume scheme. The base flow of a cylinder afterbody with base bleed is simulated. The simulation results are validated with the experimental data, and the experimental results are well reproduced. On this basis, the base flow fields with base bleed for a circular jet model and an annulus jet model are investigated by selecting the injection temperature from 830 K to 2200 K. The results show that the base pressure of the annular jet model is higher than that of the circular jet model with the changes of the injection parameter and the injection temperature. For the circular jet model, the hot gases are concentrated in the vicinity of the base. For the annular jet model, the bleed gases flow into the shear layer directly so that the hot gases are concentrated in the shear layer. The latter temperature distribution is better for the increase of base pressure.     

A study of flames with millimeter-wave radiation

It is a valuable issue to explore whether a flame can radiate microwaves, in spite of the electric field formed in the flame. Presented herein is an experimental study on a series of flames with millimeter-wave radiation in the combustion of pyrotechnic films. The pyrotechnic films were composed of ultra-fine red phosphorus (P), sodium nitrate (NaNO₃), Polyvinyl Alcohol (PVA) and some additives such as chopped carbon fibers (CFs) and aluminized glass fibers (GFs). The combustion temperatures and millimeter-wave radiation signals of the flames were measured, the millimeter-wave emissivity and spectral radiant exitance were calculated to describe the millimeter-wave radiation intensity. The results demonstrate that the flame of the pyrotechnic films based on P/NaNO₃/CFs can radiate millimeter waves, and different materials and their proportion have a great effect on the millimeter-wave radiation intensity.     

固体燃料冲压发动机飞行性能分析

固体燃料冲压发动机性能通过进气道与导弹飞行工况关联在一起,其工作过程需考虑导弹飞行参数对发动机性能的影响。与其它冲压发动机相比,固体燃料冲压发动机一个显著特点是推进剂燃烧过程不仅与推进剂配方、发动机结构和燃烧室压强有关,还取决于燃烧室入口空气参数,因此工作过程较为复杂。在国内首次建立固体燃料冲压发动机工作过程仿真模型,并分析导弹飞行马赫数和高度对发动机性能的影响规律。     

二维可压缩流动抽吸流量模型及验证

根据超声速与亚声速流动的特征,依据Prandtl-Meyer膨胀波理论,根据背压与来流静压确定膨胀波后的马赫数,获得了质量抽吸流率,并导出了壅塞发生的条件,建立了二维超声速抽吸模型;根据冲量定理,假定气体从主流区域到抽吸腔流态的变化是由于压差的冲量作用,建立了亚声速抽吸模型,并且进一步阐述了亚声速抽吸壅塞发生的机制。计算流体力学验证表明亚声速抽吸冲量模型的偏差较大,因此通过数值拟合模型来描述亚声速抽吸流动。该研究为三维抽吸研究提供了参考。     

Burning rate and other characteristics of strontium titanate (SrTiO3) supplemented AP/HTPB/Al composite propellants

In a quest of search for a new burning rate modifier for composite propellant, strontium titanate (SrTiO₃), a perovskite oxide has been chosen for evaluation in a composite propellant formulation based on its other catalytic applications. Initially, SrTiO₃ was characterized for particle size, morphology and material/phase identification (using XRD). By varying SrTiO₃ content in a standard composite propellant, different compositions were prepared and their performance and processing parameters like the end of mix (EOM) viscosity, mechanical properties, density, burning rate, pressure exponent (n-value), etc. were measured. The results reveal that 2% SrTiO₃ causes more than 12% enhancement in propellant burning rate (at 70 ksc pressure) in comparison to the standard propellant composition. The pressure exponent also increases to 0.46, whereas the standard composition was having its value as 0.35.     

Mg／PTFE／添加剂红外诱饵剂的红外辐射性能研究

研究了Mg／PTFE／添加剂红外诱饵剂的压药直径和压药密度对红外辐射性能的影响。在同一种配方下,经过试验发现辐射强度同质量燃烧速度成线性关系;辐射强度随着压药密度的增加而减小,最后趋于稳定;有效辐射率随着压药密度和压药直径的改变变化不大,表明压药密度和压药直径对有效辐射率基本没有影响。     

有排气弹丸底部阻力的估算方法

综合了国内外有关排气温度、分子量和来流马赫数影响底部阻力的实验和理论成果,采用人工神经网络方法处理了实验数据,提供出一个有排气弹丸底部阻力的工程估算方法。     

液体推进剂液滴高压蒸发研究

本文改进了现有的液体推进剂液滴高压蒸发模型,提出了一个计算高压下液滴蒸发时环境介质气体在液滴中溶解的子模型,该模型中采用了改进的R-K气体状态方程。利用本模型对丙烷在氮气中的高压蒸发进行了计算。结果表明在高压下液滴蒸发时间随压力和环境温度的增加而减小,当压力超过某临界值时,液滴将达到超临界状态。高压下环境介质气体在液滴中的溶解是非常明显的,并且压力愈高溶解性愈大,因此在推进剂高压燃烧中必须考虑溶解性对于液滴蒸发的影响。     

最小自由能法计算烟火药剂热值

烟火药剂的热值计算在烟火研究领域有着重要的作用．本文根据最小自由能原理,通过一系列基本假设计算出了体系燃烧爆炸反应后的热值,计算结果与实验衡量数据相吻合,并且程序可通过进一步完善,扩展应用于非理想气体,提高计算精度．     

Numerical investigation on cooling performance of filter in a pyrotechnic gas generator

As a key part of the pyrotechnic gas generator,the filter not only removes the particulate matter but also cools the hot gas to a safe level.This paper aims to improve the understanding of the basic heat and flow phenomenon in the gas generator.The pyrotechnic gas generator is modelling by a simplified filter structure with fiber arrays.A finite-volume model of the heat and fluid flow is proposed to simulate the detailed multi-dimensional flow and energy conversion behaviors.Several verification results are in good agreement with data in different references.Simulation results demonstrate that the filter can not only absorb heat from the gas but also cause the high intensity enhancement of the heat transfer.The per-formance difference between inline and staggered arrays is also discussed.The findings of the study put a further prediction tool for the understanding and design of the filter system with fibers.     

Research on 2D Model of Capillary Discharge Plasma

The physical process of capillary discharge in a PE tube utilized in electro-thermal-chemical(ETC)guns was investigated.ETC guns can enhance the ignition and combustion of propellant in order to reduce the ignition delay and increase muzzle velocity of the projectile.A key component in ETC gun is the capillary plasma source.In this paper,a 2D steady state model of discharge was built by using magnetic hydrodynamics method.It took the plasma energy balance,material ablation,mass and momentum conservations in a quasi-neutral plasma region into account.Also,the effect of different compositions and PE concentration distribution were considered.In order to evaluate the validation of this model,the simulation results are compared with former works.     

复合固体推进剂颗粒填充模型及其统计特性分析

复合固体推进剂属于高填充比颗粒类复合材料,氧化剂和金属颗粒在基体中的随机分布使其在细观尺度具有非均质的特点。从细观尺度研究固体推进剂燃烧及力学性能时,必须考虑颗粒级配、空间分布和种类等因素的影响。采用分子动力学方法,以硝酸酯增塑聚醚高能复合固体推进剂为研究对象,将固体颗粒模型化为球形,生成其在基体内随机分布的颗粒填充模型。利用Monte-Carlo算法模拟计算颗粒填充模型细观结构的两点概率函数,并研究了颗粒填充体积分数、尺寸与级配等参数对其的影响规律。从统计意义上给出具有各态历经性、统计均匀性和各向同性特点的颗粒填充构型最小周期性代表体元尺寸,可有效减小后续研究的计算量,节约计算成本。所构建的推进剂细观几何构型及对最小周期性代表体元尺寸的计算为后续开展复合固体推进剂细观尺度燃烧、燃面处铝团聚及力学性能数值研究奠定了基础。     

单基发射药的热自燃数值模拟与其剩余能量变化研究

建立了单基发射药柱热自燃的数学模型 ,根据模型利用数值模拟的方法计算了单基发射药的中心温度与其剩余能量 ,并对中心温度的模拟结果与实验结果进行了比较。解决了其热分解动力学参数的非唯一性问题 ,为装填有单基发射药各种弹药的热自燃计算提供了依据