华东烧结模型的数学计算(Ⅱ)

通过热力学分析和数学计算，讨论颗粒呈现面心立方堆积方式时，华东烧结模型中膨胀机制和收缩机制对烧结体总表面能的作用和总孔隙度比变化的影响，计算表明烧结过程中收缩机制占主导地位。     

Si3 N4基复相陶瓷天线罩材料的制备及性能

基于高马赫数导弹天线罩为应用背景,以Si粉、BN粉、SiO2粉为主要原料,采用反应烧结法制备Si3N4基复相陶瓷材料,探讨了原料组成、成型工艺及坯体密度对材料性能的影响。试验结果表明:当原料中Si、BN和SiO2分别为55%、30%和10%时,材料强度可达96.7MPa,断裂韧性可达1.80MPa.m1/2。同时材料具有良好的介电性能及热物理性能。     

冲击波活化热压烧结氮化硅粉末

对Si3 N4粉末实现了三种不同压力的冲击波预先处理 ,而后采用三种不同的热压烧结条件制得Si3 N4陶瓷。运用SEM ,TEM ,HRTEM和XRD等手段分析了粉末和陶瓷的结构特性 ,同时测试了材料的性能。结果表明 :冲击波压力没有导致Si3 N4粉末的相变 ,TEM观察表明Si3 N4晶粒中有大量的位错及位错群 ,冲击波的作用主要是通过引入大量位错和其他缺陷促进致密化过程 ,提高陶瓷材料的机械性能。经过40GPa冲击波活化 1 80 0℃热压烧结的Si3 N4陶瓷性能最好 ,弯曲强度达 1 1 0 7.2MPa ,断裂韧性达 1 2 .2 0MPa .m1/2 。     

烧结温度对 Cf/SiC 复合材料界面的影响

系统地研究了烧结温度对Cf/SiC复合材料界面和力学性能的影响.结果表明,烧结温度较低(1700℃)时,由于复合材料的烧结性差,纤维与基体间仅仅为一种机械结合,因此纤维与基体间结合很弱,从而导致复合材料力学性能低.烧结温度提高至1800℃后,由于适量的富碳界面相不仅可避免纤维与基体间的直接结合,而且使纤维与基体间的结合强度适中,因而复合材料具有很好的力学性能.进一步提高烧结温度至1850℃或更高温度时,由于界面相与纤维间的反应加重,纤维本身性能大大降低.同时,纤维与基体间结合强度提高,因此复合材料的力学性能大大降低.     

华东烧结模型的数学计算(I)

利用热力学分析和数学计算,给出颗粒表面能的表达式,依此讨论了颗粒的２种典型堆集和华东烧结模型中膨胀机制与收缩机制对烧结体总表面能的作用效果,为工程应用提供依据。     

高比重钨合金的烧结成形与组织性能研究

采用液相烧结成形工艺制备了90W-Ni-Fe合金棒,通过分析烧结态钨合金的组织形貌和力学性能,观察合金的断口组织形貌,研究了烧结工艺对高比重钨合金组织性能的影响,认为减少W-W界面,增加W-W界面的结合强度,是提高烧结态钨合金力学性能的有效途径。     

Coating processes towards selective laser sintering of energetic material composites

This research aims to contribute to the safe methodology for additive manufacturing (AM) of energetic materials. Coating formulation processes were investigated and evaluated to find a suitable method that may enable selective laser sintering (SLS) as the safe method for fabrication of high explosive (HE) compositions. For safety and convenience reasons, the concept demonstration was conducted using inert explosive simulants with properties quasi-similar to the real HE. Coating processes for simulant RDX-based microparticles by means of PCL and 3,4,5-trimethoxybenzaldehyde (as TNT simulant) are reported. These processes were evaluated for uniformity of coating the HE inert simulant particles with binder materials to facilitate the SLS as the adequate binding and fabrication method. Suspension system and single emulsion methods gave required particle near spherical morphology, size and uniform coating. The suspension process appears to be suitable for the SLS of HE mocks and potential formulation methods for active HE composites. The density is estimated to be comparable with the current HE compositions and plastic bonded explosives (PBXs) such as C4 and PE4, produced from traditional methods. The formulation method developed and understanding of the science behind the processes paves the way toward safe SLS of the active HE compositions and may open avenues for further research and development of munitions of the future.     

华东烧结模型的数学计算(Ⅲ)

通过热力学分析和计算,讨论等径球(椭球)与均匀分布不等径球(椭球)的体心正方堆积的烧结体积和表面能的变化,包括华东烧结模型中膨胀机制和收缩机制,对烧结体总表面能变化的作用和影响,发现随着烧结过程的进行,烧结收缩机制逐渐占主导地位。