某型引信压电陶瓷加速老化试验

压电陶瓷作为压电引信的关键元件,其贮存可靠性至关重要。为研究贮存对压电陶瓷性能变化的影响,进行了历时176天的某型引信用压电陶瓷加速老化试验。根据试验结果研究了陶瓷的压电参数随试验条件和老化时间变化的规律,探索了压电陶瓷的贮存可靠性和可靠贮存寿命。     

老化对阻燃玻璃钢燃烧性能影响初探

通过对玻璃钢阻燃技术的介绍,以及老化对玻璃钢性能的影响,提出阻燃玻璃钢材质在自然环境中同样存在因老化而出现阻燃性降低的问题。     

舰船电缆热老化寿命的研究

介绍了某船用电缆热老化寿命研究的有关试验和结果分析．对电统绝缘材料失效的判断、机械性能变化的预测,以及如何根据电缆的负载情况和周围的环境温度确定绝缘材料的老化温度等,提出了相应的观点和方法．     

长贮过程中发动机HTPB推进剂老化机理分析

为揭示固体推进剂在长期贮存过程中的老化机理,解剖了自然贮存19年贴壁浇注的端羟基聚丁二烯橡胶推进剂装药发动机,沿着药柱径向不同位置进行了取样,并采用扫描电镜、能量色散X射线光谱仪、红外吸收光谱、交联密度等多种手段对这些样品进行了测试分析。研究发现：贴壁浇注发动机药柱不同位置推进剂的老化程度不尽相同,越靠近非金属壳体位置,推进剂的老化程度越严重。进一步深入分析表明：除了丁羟胶中双键的氧化断链和端羟基的缩合等影响推进剂老化,铝粉氧化产生的铝离子会催化丁羟胶双键与氯气或水发生加成反应生成■双键和仲醇,而铝离子迁移和分布的不均匀会引起药柱老化的不均匀性。研究结果对推进剂配方设计和防老化措施的研究具有重要意义。     

耐海水高耐候丙烯酸树脂的合成及面漆性能分析

为合成耐海水与高耐候的丙烯酸树脂,选择甲基丙烯酸甲酯、甲基丙烯酸羟丁酯、丙烯酸异辛酯和丙烯酸已内酯,经引发剂作用,采用同步滴加法进行聚合反应,通过调节温度并测定酸价控制反应历程,并将合成的不同玻璃化温度的丙烯酸树脂配制成具有适当玻璃化温度梯度的耐海水面漆成膜树脂体系。选择HDT-90固化剂与丙烯酸成膜树脂作用,制备耐海水面漆涂层样品。性能测试结果表明,研制的耐海水面漆具有优良的耐候性和抗老化性。     

Transverse relaxation characteristic and stress relaxation model considering molecular chains of HTPB coating based on pre-strained thermal aging

In order to accurately describe the transverse relaxation characteristic and stress relaxation modulus of HTPB coating during pre-strain thermal aging process, a one month thermal aging test was carried out at 70 C with pre-strain of 0％, 3％, 6％ and 9％, respectively. The low-field 1H NMR and stress relaxation modulus tests were carried out for HTPB coating at different aging stages. The stress relaxation model considering the molecular chains was proposed according to the changes of crosslinking chain and dangling chain of HTPB coating during pre-strain aging. The results showed that with the increase of aging time, the decay rate of transverse relaxation curve became faster, the transverse relaxation time decreased, the value of combined parameter qMrl increased, the proportion of crosslinking chain decreased, while the proportion of dangling chain increased. Moreover, the stress relaxation modulus increased, the crosslinking network structure of HTPB coating became denser and the degree of cross-linking increased. At the initial aging stage, the pre-strain will destroy the crosslinking network structure of HTPB coating to a certain extent. With the increase of aging time, the effect of pre-strain will gradually weaken and the influence of aging on materials will gradually increase. The correlations between the stress relaxation model considering the molecular chains and the test results were more than 0.9950, which can accurately describe the stress relaxation modulus of HTPB coating during the pre-strain thermal aging process.     

A new experimental way for the monitoring of the real/equivalent in-service-time of double base rocket propellant by coupling VST and PCA

The assessment of the real in-service-time(RIST)and the equivalent in-service-time(EIST)of double base rocket propellants(DBRPs)is of utmost importance for the safe storage and use of weapon systems as well as the efficiency of the accelerated aging plans.In this work,four DBRPs with similar chemical composition and different natural aging have been artificially aged at T = 338.65 K for 4 months with sampling every 30 days.The unaged and artificially aged samples have been investigated by vacuum stability test(VST)at five isothermal temperatures(T = 333.15 K,343.15 K,353.15 K,363.15 K,and 373.15 K).The volume of the evolved gases in VST was found to decrease with natural/artificial aging.Furthermore,the VST data were treated and subjected to principal component analysis(PCA).The results showed excellent discrimination of the DBRP samples according to their stability thermal properties.Most of the variance was described by the first principal component(PC1)whose scores were linearly correlated with the natural aging durations when PCA is applied on VST data obtained at T = 363.15 K.In light of the obtained results,a new experimental way for the estimation of the real/equivalent IST was proposed,which takes into account the impact of the natural aging of the sample.The approach predicts successfully the RIST of two similar DBRPs with a relative deviation of less than 2％.At the specific heating temperature T = 338.65 K,the developed model provides more conceivable EIST values,with asymptotic behavior against artificial aging duration evolution,thus overcoming some shortcomings of the common generalized van't Hoff formula(GvH).     

On the median residual lifetime and its aging properties: A characterization theorem and applications

This paper is devoted to study several aspects of the median residual life function (MERLF). In reliability studies, it is well known that, although the MERLF have several advantages over the mean residual life function (MRLF), the MRLF has the good property of uniquely determine a life distribution whereas either the median residual life function (MERLF) or an α‐percentile residual life do not have such good property. We shall give a characterization result where knowledge of both the MERLF and the survival function on an interval does uniquely determine the distribution. Moreover, in order to apply this characterization in practical situations, we propose a method to estimate the necessary information of the survival function. Relationships between analytical properties of the survival function and its associated MERLF are also obtained. Bryson and Siddiqui [J Am Statist Assoc 64 (1969), 1472–1483] proved relationships among seven criteria for aging, out of which two contained the MRLF (decreasing MRLF and net decreasing MRLF). In this paper, we prove that the same pattern of relationships holds if the MRLF is replaced by the MERLF. We also examine the aging criteria corresponding to an increasing MERLF and show that there is no relation between the behavior (increasing or decreasing) of the MERLF and of the MRLF. © 2005 Wiley Periodicals, Inc. Naval Research Logistics, 2005     

含内聚空洞固体发动机药柱的寿命预估

为了对含内聚空洞固体导弹发动机的贮存寿命进行预估,采用加速老化试验,得到该推进剂最大延伸率随贮存时间的变化规律;应用三维粘弹性有限元分析方法,对含内聚空洞的发动机贮存一定时间后直接点火发射过程进行数值仿真,从中获得发动机药柱在点火增压和轴向过载联合作用下的最大Von Mises应变.将不同贮存期药柱的最大Von Mises应变值与推进剂的最大延伸率进行对比,利用结构完整性评估准则,给出了某发动机药柱不同贮存期间内聚空洞大小的允许值.该方法可为含内聚空洞固体发动机的判废提供定量参考.